MATERIAL DATA SHEET Material

FDM Data Sheet

™

ULTEM 9085 Resin

®

FDM Thermoplastic Filament

Fit for High-Performance Applications

The information presented are typical values intended for reference and comparison purposes only. They should not be used for design specifications or quality control purposes.

Overview

ULTEM™ 9085 resin filament is a PEI (polyetherimide) thermoplastic FDM material. It features a high strength-to-weight ratio, high thermal and chemical resistance, and meets multiple aerospace and railway industry standards for flame, smoke and toxicity (FST) characteristics. Available colors are Natural, Black, Red, Jana White, White 7362, Dream Gray, Gunship Gray and Aircraft Gray.

ULTEM™ 9085 resin CG (Certified Grade-only available in Natural) meets more stringent test criteria and possesses documented traceability from filament back to raw material lot number. Included documentation:

• Certificate of Analysis — for both raw material and filament are supplied, documenting test results and identification to match filament manufacturing lot number to raw material batch number.

• ® and industry specifications. Certificate of Conformance — confirms that the material is

Typical applications include production parts and functional manufactured in compliance to approved Stratasys

prototypes.

Contents:

Overview ... 2 Ordering Information ... 3

Physical Properties ... 6 Mechanical Properties ... 7

UV Aging ... 16 Performance at Temperature ... 17

Flame, Smoke and Toxicity Test Results ... 18 Outgassing ... 21

Fire Protection for Railway Vehicles ... 21 Fire Protection for Devices and Appliances ... 23

Fire Protection of Buses ... 24 Appendix ... 25

Ordering Information

Table 1: Printer and Support Material Compatibility

ULTEM™ 9085 resin colors (Red, Jana White, White 7362, Dream Gray, Gunship Gray, and Aircraft Gray) are only available on the F900 and Fortus 450mc with the T16 model tip using a 0.254 mm (0.010 in.) layer height. ULTEM™ 9085 resin colors Red and Aircraft Gray are enabled at a layer height of 0.330 mm (0.013 in.) with the T20 tip on the F900 and Fortus 450mc.

Build Sheet

Fortus High Temperature Build Sheets

• 0.51 x 660 x 965 mm (0.02 x 26 x 38 in.)

• 0.51 x 406 x 470 mm (0.02 x 16 x 18.5 in.)

F3300 High Temperature Build Sheets

• 0.51 x 660 x 711 mm (0.02 x 26 x 28 in.)

System Requirements1 Fortus 450mc

Fortus 450mc • Hardened machine upgrade (only required for hardened head)

• Hardened machine upgrade (only required for hardened head) • Standard Fortus 450mc head (natural, black, CG, Validated Material colors)

• F3000 Series Extruder Drive

• Standard Fortus 450mc head (natural, black, CG, Validated Material colors)

• Hardened Fortus 450mc head (Validated Material colors)

• Standard Hot Ends

• Hardened Fortus 450mc head (Validated Material colors) • ULTEM™ 9085 resin material license (included if new system) • All Materials license (Required for Validated Material colors, included if new system)

1 Contact your Stratasys representative for ordering information.

Table 2: ULTEM™ 9085 Resin Ordering Information

Physical Properties

Values are measured as printed on the F900 with a 0.254 mm (0.010 in.) layer height. XY, XZ and ZX orientations were tested. For full details refer to the Stratasys Materials Test Procedure on www.stratasys.com. DSC and TMA curves can be found in the Appendix.

Table 3: ULTEM™ 9085 Resin Natural Physical Properties

178.2,^{\circ}!\mathsf{C},(352.8,^{\circ}!\mathsf{F})

170.2;^{\circ}\mathrm{C}

178.4,^{\circ}\mathbb{C},

176.9\ ^{\circ}\mathbb{C}

(-50,{}^{\circ}\ !{\mathsf{C}},!{\mathsf{t o}},\ }60,{}^{\circ}!\ !mathsf\ C{)}

(60,^{\circ}\mathbb{C}

160;^{\circ}\mathrm{C})

80,^{\circ}\mathrm{C})

(-50,^{\circ}\mathrm{C}

32.31\upmu\mathsf{m}/[\mathsf{m}^{\up}\mathsf{\ }mathsf{{c C}}]

17.95,{upmuup}{\upmu n}/[{\sf n}}}&{{{{\sfsf^n\ }}{\upamma}]

(80,^{\circ}\mathbb{C}

(24.94,\up\up{\ mu i!/}[\mathsf{i n}^{\star\circ}\mathsf{F}])

160;^{\circ}\mathrm{C})

(-50,^{\circ}\mathrm{C}

30,^{\circ}\mathrm{C})

(30,^{\circ}\mathbb{C}

(-50,^{\circ}\mathrm{C}

165,^{\circ}\mathrm{C})

80,^{\circ}\mathrm{C)}

\mathtt{A S T M}

(80\ {{{}}{}^{\circ}}\mathbb{C}

40.2,\upmu\mathsf{m}/[\mathsf{m}^{\star}mathsf C

160;^{\circ}\mathrm{C})

\ {mathcal Q0},^{\circ}\mathbb{C}

6.89{^star{star}}0^{15},{\Omega}{\cdot{\mathsf{c m}}}

\text{cled}600,^{\circ}\mathbb{C}

\text{cled C300}^{\circ}\mathbb{C}

\ {big@}0\ {{}^^{\circ}C}

\ {big@}30\ {{}}{\ }^{\circ}\mathbb{C}

0.121;\mathsf{m m}^{2}/\mathsf{s}

1.88^{\star}10^{\cdot4},n^{2}/s

1.72^{\star}10^{\ 4},\mathsf{i n}^{2}/\mathsf{s}

Mechanical Properties

Samples, natural and black, were printed with 0.254 mm (0.010 in.), 0.3302 mm (0.013 in.), and 0.508 mm (0.020 in.) layer heights on the F900 and Fortus 450mc. For the full test procedure please see the Stratasys Materials Test Procedure.

Flat (XY) On Edge (XZ) Upright (ZX)

Print Orientation

Parts created using FDM are anisotropic as a result of the printing process. Below is a reference of the different orientations used to characterize the material.

Tensile Curves

A = Tensile at break, elongation at break (no yield point) B = Tensile at yield, elongation at yield

B = Tensile at yield, elongation at yield C = Tensile at break, elongation at break

Table 4: ULTEM™ 9085 Resin Natural Mechanical Properties - F900 - T16 Tip

1 Values in parentheses are standard deviations.

Table 5: ULTEM™ 9085 Resin Natural Mechanical Properties - F900 - T16A Tip

1 Values in parentheses are standard deviations.

Table 6: ULTEM™ 9085 Resin Natural Mechanical Properties - F900 - T20 Tip

1 Values in parentheses are standard deviations.

Table 7: ULTEM™ 9085 Resin Natural Mechanical Properties - F900 - T40A Tip

1 Values in parentheses are standard deviations.

• ZX D638 coupons were water jetted from printed plaques. (Coupon dimensions: ~165 x 22 x 5 mm (6.500 x 0.875 x 0.200 in.)) ** XZ D638 coupons for T40A tip were larger than standards Stratasys tensile coupons. (As printed coupon dimensions: ~165 x 22 x 5 mm (6.500 x 0.875 x 0.200 in.))

** XZ D638 coupons for T40A tip were larger than standards Stratasys tensile coupons. (As printed coupon dimensions: ~165 x 22 x 5 mm (6.500 x 0.875 x 0.200 in.))

Table 8: ULTEM™ 9085 Resin Black Mechanical Properties - F900 - T16 Tip

1 Values in parentheses are standard deviations.

Table 9: ULTEM™ 9085 Resin Black Mechanical Properties - F900 - T20 Tip

1 Values in parentheses are standard deviations.

Table 10: ULTEM™ 9085 Resin Black Mechanical Properties - F900 - T40A Tip

1 Values in parentheses are standard deviations.

• ZX D638 coupons were water jetted from printed plaques. (Coupon dimensions: 6.500 x 0.875 x 0.200 inches (165 x 22 x 5 mm)) ** XZ D638 coupons for T40A tip were larger than standards Stratasys tensile coupons. (As printed coupon dimensions: 6.500 x 0.875 x 0.200 inches (165 x 22 x 5 mm))

** XZ D638 coupons for T40A tip were larger than standards Stratasys tensile coupons. (As printed coupon dimensions: 6.500 x 0.875 x 0.200 inches (~165 x 22 x 5 mm))

Table 11: ULTEM™ 9085 Resin Natural Mechanical Properties - Fortus 450mc - T16A Tip

1 Values in parentheses are standard deviations.

Table 12: ULTEM™ 9085 Resin Black Mechanical Properties - Fortus 450mc - T20 Tip

1 Values in parentheses are standard deviations.

UV Aging

Table 13: UV Aging of ULTEM™ 9085 Resin - Fortus F900 - T16A Tip

ULTEM™ 9085 resin was tested before and after UV exposure. Ten ASTM D638 upright (ZX) dogbones were tested in tensile after UV exposure and an additional 10 ASTM D638 ZX dogbones were the control (no UV exposure). The UV exposed samples were cycled in the QUV chamber per ASTM G154 (Standard Practice for Operation Fluorescent UV Light Apparatus for Exposure of Nonmetallic Materials) for 1,000 hours, alternating for eight hours at 60 ˚C (140 ˚F) and four hours at 50 ˚C (122 ˚F) with humidity and condensation. The increase in stress at break is from the control samples. For more information see the Impact of UV Exposure on FDM Materials white paper.

60\ ^{\circ}\mathrm{c}

50\ ^{\circ}\mathrm{c}

140~{}^{\circ}!\mathsf{F})

Performance at Temperature

ULTEM™ 9085 resin was tested at various temperatures. Ten ASTM D638 upright (ZX) T16 dogbone coupons were tested in tensile. The percent change from the reported room temperature results are listed below. For more information, see the Impact of Temperature on High-Performance FDM Materials white paper.

Table 14: Performance of ULTEM™ 9085 Resin at Temperatures - T16 Tip

ULTEM™ 9085 resin was tested for Flame, Smoke, and Toxicity (FST), Outgassing, NFPA 130, EN 45545-2, and UN ECE Regulation 118. These tests were done to show that ULTEM™ 9085 resin complies to the tested standard, not to show certification to any specific standard. It is suggested that additional testing be conducted if there are any questions about how ULTEM™ 9085 resin will perform for a specific part.

Flame, Smoke and Toxicity

ULTEM™ 9085 resin, natural (T20 tip and T16A tip) and black (T16 tip), were printed on the Stratasys F900 and tested per 14 CFR 25.853, BSS 7238 and 7239, and AITM 2.0007B and 3.0005. The testing establishes that this material meets requirements for:

• 60s and 12s Vertical Burn • Toxic Gas Emission • Heat Release Rate of Cabin Materials

Table 15: ULTEM™ 9085 Resin Flame, Smoke and Toxicity Test Results

• 15s Horizontal Burn • Smoke Density

Table 16: ULTEM™ 9085 Resin Flame, Smoke and Toxicity Test Results

Table 17: ULTEM™ 9085 Resin Flame, Smoke and Toxicity Test Results

Outgassing

ULTEM™ 9085 resin, natural and black, was printed with a T20 and T16 tip on the Stratasys F900 and tested per ASTM E595. Full report available upon request.

Table 18: ULTEM™ 9085 Resin Outgassing Test Results

1 Observations apply to all tested samples.

Fire Protection of Railway Vehicles NFPA 130

ULTEM™ 9085 resin CG was printed with a T16A tip on the Stratasys F900 using single contour and +45/-45 solid rasters, which are typical default settings and tested per NFPA 130. *

* It should be noted that products with other wall thicknesses and/or printed at different machines and with different settings (orientation/filling/tip size) may perform differently.

• Further testing should be done by the customer to make sure the material fits their final application.

Table 19: ULTEM™ 9085 Resin CG NFPA 130 Fixed Guideway Transit and Passenger Transit Systems Test Results

Fire Protection of Railway Vehicles EN 45545-2

ULTEM™ 9085 resin CG was printed with a T16A tip on the Stratasys F900 using single contour and +45/-45 solid rasters, which are typical default settings and tested per EN 45545-2. The limited testing done establishes that this material meets requirements for:

• R1, R2, R3, R6, R7, R17: HL1/2/3 at 25 mm thick in XY and XZ orientations

• R2, R3, R17: HL1/2/3 at 5 mm thick in XY orientation

• Not classified at 5 mm thick in XZ orientation

• R22: HL1/2 at 0.508 mm thick in XY orientation

• R22: HL1/2/3, 1 mm to 10.5 mm in XY orientation

• R23: HL1/2/3, 0.508 mm to 10.5 mm in XY orientation

* Additional tests are in progress. Please consult Stratasys Application Engineers to learn more.

Additional tests are in progress. Please consult Stratasys Application Engineers to learn more.

* It should be noted that products with other wall thicknesses and/or printed at different machines and with different settings

It should be noted that products with other wall thicknesses and/or printed at different machines and with different settings (orientation/filling/tip size) may perform differently.

* Further testing should be done by the customer to make sure the material fits their final application. Table 20: ULTEM™ 9085 Resin CG Fire Protection of Railway Vehicles Test Results for R1 Requirement Set

Table 21: ULTEM™ 9085 Resin CG Fire Protection of Railway Vehicles Test Results for R22/23 Requirement Set

\mathsf{D}_{\mathsf{s}}(4)

\mathrm{V o F}_{4}

\mathrm{c l T}_{\mathsf L L\mathsf}

%0{}_{2}

Fire Protection for Devices and Appliances UL 94

Samples of ULTEM™ 9085 resin were 3D printed on a Stratasys F900 printer using a T16 tip and green flag settings and tested per UL 94 flammability standards. The results showed that ULTEM 9085 achieved an HB rating for samples printed at a thickness of 3 mm as per UL 94 - Section 7. Additionally, the material earned a V-0 rating for samples printed at a thickness of 0.508 mm in the XZ orientation and 1 mm in the ZX orientation as per UL 94 - Section 8.

Table 22: ULTEM™ 9085 resin UL 94 Flammability Test Results

Fire Protection of Buses UN ECE Regulation 118

ULTEM™ 9085 resin CG was printed with a T16 tip on the Stratasys F900 using single contour and +45/-45 solid rasters, which are typical default settings and tested per EN-45545-2.

• Orientation: Flat XY

• Sample thickness: 3mm

Table 23: ULTEM™ 9085 Resin CG Fire Protection of Buses Test Results

Appendix

Validated Materials

Stratasys Validated Materials are developed by Stratasys or a third-party provider, meet Stratasys quality standards, and have received basic reliability testing for use with Stratasys FDM printers.

Table 24: Colored ULTEM™ 9085 Resin Validated Materials

1 Values in parentheses are standard deviations.

1 Values in parentheses are standard deviations.

Validated Material - ULTEM™ 9085 Resin Dream Gray (AIC 2.49), F900, T16

Validated Material - ULTEM™ 9085 Resin Jana White (AIC 12.36), Fortus 450mc, T16

Validated Material - ULTEM™ 9085 Resin Jana White (AIC 12.36), F900, T16

1 Values in parentheses are standard deviations.

Validated Material - ULTEM™ 9085 Resin Red, F900, T16

1 Values in parentheses are standard deviations.

Flame, Smoke, and Toxicity

ULTEM™ 9085 resin White, Jana White, Aircraft Gray, Dream Gray, Gunship Gray, and Red were all printed on the Stratasys F900 with the T16 tip. For more information or for a detailed test report please contact a Stratasys representative.

Table 25: ULTEM™ 9085 Flame, Smoke, and Toxicity Test Results

12 Second Vertical Ignition per 14 CFR 25.853(a), Appendix F, Part I, Paragraph (a)(1)(ii)

60 Second Vertical Ignition per 14 CFR 25.853(a), Appendix F, Part I, Paragraph (a)(1)(i)

15 Second Horizontal Ignition per 14 CFR 25.853(a), Appendix F, Part I, Paragraph (a)(1)(iv)(v)

Figure 1: 2nd heating scan DSC data for ULTEM™ 9085 resin, natural.

DSC

Figure 2: 2nd heating scan DSC data for ULTEM™ 9085 resin, black. DSC

Figure 3: Dimension change data as a function of temperature for ULTEM™ 9085 resin, natural, flat (XY).

TMA

Figure 4: Dimension change data as a function of temperature for ULTEM™ 9085 resin, natural, upright (XZ).

TMA

Figure 6: Dimension change data as a function of temperature for ULTEM™ 9085 resin, black, upright (XZ). TMA

Figure 6: Dimension change data as a function of temperature for ULTEM™ 9085 resin, black, upright (XZ). TMA

Figure 7: Overlay of the dimension change data for all the ULTEM™ 9085 resin samples.

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MATERIAL DATA SHEET

FDM